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Anne Marie de Grosbois 《Environmental Geology》2008,54(6):1353-1354

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Anne Marie de Grosbois 《Environmental Geology》2008,55(3):699-703

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Garnet growth at high- and ultra-high pressure conditions and the effect of element fractionation on mineral modes and composition   总被引：4，自引：0，他引：4  

Matthias Konrad-Schmolke  Patrick J. O'Brien  Christian de Capitani  Dennis A. Carswell   《Lithos》2008,103(3-4):309-332

In this paper we show that thermodynamic forward modelling, using Gibbs energy minimisation with consideration of element fractionation into refractory phases and/or liberated fluids, is able to extract information about the complex physical and chemical evolution of a deeply subducted rock volume. By comparing complex compositional growth zonations in garnets from high-and ultra-high pressure samples with those derived from thermodynamic forward modelling, we yield an insight into the effects of element fractionation on composition and modes of the co-genetic metamorphic phase assemblage. Our results demonstrate that fractionation effects cause discontinuous growth and re-crystallisation of metamorphic minerals in high pressure rocks. Reduced or hindered mineral growth at UHP conditions can control the inclusion and preservation of minerals indicative for UHP metamorphism, such as coesite, thus masking peak pressure conditions reached in subducted rocks.Further, our results demonstrate that fractional garnet crystallisation leads to strong compositional gradients and step-like zonation patterns in garnet, a feature often observed in high-and ultra-high pressure rocks. Thermodynamic forward modelling allows the interpretation of commonly observed garnet growth zonation patterns in terms of garnet forming reactions and the relative timing of garnet growth with respect to the rock's pressure–temperature path. Such a correlation is essential for the determination of tectonic and metamorphic rates in subduction zones as well as for the understanding of trace element signatures in subduction related rocks. It therefore should be commonplace in the investigation of metamorphic processes in subduction zones.  相似文献   

Origin of the Tongshankou porphyry–skarn Cu–Mo deposit,eastern Yangtze craton,Eastern China: geochronological,geochemical, and Sr–Nd–Hf isotopic constraints     

Jian-Wei Li  Xin-Fu Zhao  Mei-Fu Zhou  Paulo Vasconcelos  Chang-Qian Ma  Xiao-Dong Deng  Zorano Sérgio de Souza  Yong-Xin Zhao  Gang Wu 《Mineralium Deposita》2008,43(3):315-336

The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an ⁴⁰Ar/³⁹Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm), Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However, they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions, with (⁸⁷Sr/⁸⁶Sr) _t  = 0.7062–0.7067, ɛ _Nd(t) = −4.37 to −4.63, (¹⁷⁶Hf/¹⁷⁷Hf) _t  = 0.282469–0.282590, and ɛ _Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe³⁺–Fe²⁺–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim.  相似文献   

Crowdsourcing a cyclist perspective on suggested recreational paths in real-world networks     

Kevin Baker  Kristien Ooms  Steven Verstockt  Pascal Brackman  Philippe De Maeyer  Rik Van de Walle 《制图学和地理信息科学》2017,44(5):422-435

ABSTRACT

Routing and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative.  相似文献   

Recent trends in annual snowline variations in the northern wet outer tropics: case studies from southern Cordillera Blanca,Peru     

Bijeesh?Kozhikkodan?VeettilEmail author  Shanshan?Wang  Ulisses?Franz?Bremer  Sergio?Florêncio?de?Souza  Jefferson?Cardia?Sim?es 《Theoretical and Applied Climatology》2017,127(1-2):213-227

TL-moments approach has been used in an analysis to identify the best-fitting distributions to represent the annual series of maximum streamflow data over seven stations in Johor, Malaysia. The TL-moments with different trimming values are used to estimate the parameter of the selected distributions namely: Three-parameter lognormal (LN3) and Pearson Type III (P3) distribution. The main objective of this study is to derive the TL-moments (t ₁,0), t ₁?=?1,2,3,4 methods for LN3 and P3 distributions. The performance of TL-moments (t ₁,0), t ₁?=?1,2,3,4 was compared with L-moments through Monte Carlo simulation and streamflow data over a station in Johor, Malaysia. The absolute error is used to test the influence of TL-moments methods on estimated probability distribution functions. From the cases in this study, the results show that TL-moments with four trimmed smallest values from the conceptual sample (TL-moments [4, 0]) of LN3 distribution was the most appropriate in most of the stations of the annual maximum streamflow series in Johor, Malaysia.  相似文献   

Future emissions of marine halogenated very-short lived substances under climate change     

Franziska?Ziska  Birgit?QuackEmail author  Susann?Tegtmeier  Irene?Stemmler  Kirstin?Krüger 《Journal of Atmospheric Chemistry》2017,74(2):245-260

Halogenated Very Short-lived Substances (VSLS), such as bromoform, dibromomethane and methyl iodide, are naturally produced in the oceans and are involved in ozone depletion in the troposphere and the stratosphere. The effect of climate change on the oceanic emissions of these compounds is not well quantified. Based on present-day observed global oceanic and atmospheric concentrations, and historic and future data from three CMIP5 models, past and future sea-to-air fluxes of these VSLS are calculated. The simulations are used to infer possible effects of projected changes of physical forcing on emissions in different oceanic regimes. CMIP5 model output for 1979–2100 from the historical scenario and the RCP scenarios 2.6 and 8.5 are used as input data for the emission calculations. Of the parameters that have the main influence on the sea-to-air fluxes, the global sea surface temperatures show a steady increase during the twenty-first century, while the projected changes of sea surface wind speed is very small. The calculated emissions based on the historical CMIP5 model runs (1979–2005) increased over the 26 year period and agree well with the emissions based on ERA-Interim data. The future sea-to-air fluxes of VSLS generally increase during the twenty-first century under the assumption of constant concentration fields in the ocean and atmosphere. The multi-model mean global emissions of bromoform increase by 29.4% (9.0%) between 1986 and 2005 and 2081–2100 under RCP 8.5 (2.6) and dibromomethane and methyl iodide emissions increase by 23.3% (6.4%) and 5.5% (1.5%), respectively. Uncertainties of the future emission estimates, driven by ongoing environmental changes such as changing oceanic productivity (not considered in this study) are discussed.  相似文献   

Actor-Based Design of a Management System for the Elephant Marsh Fishery in Malawi     

Ishmael B. M. Kosamu  Wouter T. de Groot  Patrick S. Kambewa 《社会与自然资源》2017,30(3):299-314

In Malawi, fishing community user groups known as beach village committees, traditional chiefs, government officers, and fishers are the key players in fisheries management. Fish catch trends at the Elephant Marsh Fishery in southern Malawi are declining. Based on interviews and participant observation, this article uses an actor-based framework (known as Action-in-Context) to unveil the issues that are crucial in devising a sustainable governance system for the fishery. We establish and propose that the key social variables for the design of a three-pillared (locally based, weak, and amorphous) resilient institution for sustainability of the Elephant Marsh Fishery are (i) the social reputation of the leaders of local fishery institutions (beach village committee leaders), and (ii) the power dynamics between traditional chiefs and these local fishery leaders. We end the article by exploring the implications of the findings on the sustainability of the fishery under rising resource pressure.  相似文献   

A record of the Messinian salinity crisis in the eastern Ionian tectonically active domain (Greece,eastern Mediterranean)          下载免费PDF全文

Vasileios Karakitsios  Marco Roveri  Stefano Lugli  Vinicio Manzi  Rocco Gennari  Assimina Antonarakou  Maria Triantaphyllou  Konstantina Agiadi  George Kontakiotis  Nefeli Kafousia  Marc de Rafelis 《Basin Research》2017,29(2):203-233

This integrated study (field observations, micropalaeontology, magnetostratigraphy, geochemistry, borehole data and seismic profiles) of the Messinian–Zanclean deposits on Zakynthos Island (Ionian Sea) focuses on the sedimentary succession recording the pre‐evaporitic phase of the Messinian salinity crisis (MSC) through the re‐establishment of the marine conditions in a transitional area between the eastern and the western Mediterranean. Two intervals are distinguished through the palaeoenvironmental reconstruction of the pre‐evaporitic Messinian in Kalamaki: (a) 6.45–6.122 Ma and (b) 6.122–5.97 Ma. Both the planktonic foraminifer and the fish assemblages indicate a cooling phase punctuated by hypersalinity episodes at around 6.05 Ma. Two evaporite units are recognized and associated with the tectonic evolution of the Kalamaki–Argassi area. The Primary Lower Gypsum (PLG) unit was deposited during the first MSC stage (5.971–5.60 Ma) in late‐Messinian marginal basins within the pre‐Apulian foreland basin and in the wedge‐top (<300 m) developed over the Ionian zone. During the second MSC stage (5.60–5.55 Ma), the PLG evaporites were deeply eroded in the forebulge–backbulge and the wedge‐top areas, and supplied the foreland basin's depocentre with gypsum turbidites assigned to the Resedimented Lower Gypsum (RLG) unit. In this study, we propose a simple model for the Neogene–Pliocene continental foreland‐directed migration of the Hellenide thrusting, which explains the palaeogeography of the Zakynthos basin. The diapiric movements of the Ionian Triassic evaporites regulated the configuration and the overall subsidence of the foreland basin and, therefore, the MSC expression in this area.  相似文献   

Alonso's Theory of Movements: Developments in Spatial Interaction Modeling   总被引：1，自引：1，他引：1  

Jacob J. de Vries  Peter Nijkamp  Piet Rietveld 《Journal of Geographical Systems》2001,3(3):233-256

 The Spatial Interaction Model proposed by Alonso as “Theory of Movements” offers an innovative specification of spatial origin-destination flow models. Equations for flows between regions, total outflow from and total inflow to a region are linked by balancing factors. This paper presents a consistent formulation of Spatial Interaction Models in the Wilson tradition and Alonso's Theory of Movements. The paper is intended as an introduction to the model and a review of␣the state of the art. Besides it is argued that simultaneous equation techniques are required to estimate the so-called systemic parameters. Received: 21 May 2000 / Accepted: 18 January 2001  相似文献